Type Occurrence of Vermiculite

Place Of Occurrence – Millbury, Worcester Co., Massachusetts, USA
Year Of Discovery – 1824 (18th Century)
Occurrence – Forms as an alteration product of biotite or phlogopite, by weathering or hydrothermal action. Vermiculite is mined as a natural insulation material worldwide.

Crystallography of Vermiculite

Crystal System – Monoclinic
Cell Parameters – a = 5.24Å, b = 9.17Å, c = 28.6Å, β = 94.6°
Ratio – a:b:c = 0.571 : 1 : 3.119
Unit Cell Volume – V 1,369.83 ų (Calculated from Unit Cell) Vermiculite for Crystallography Radiation – Copper Kα ;Horizontal Axis: 5° to 90° ; Vertical Axis: 100%

Optical Data of Vermiculite

Type – Monoclinic
RI values – n α = 1.525 – 1.561 nβ = 1.545 – 1.581 nγ = 1.545 – 1.581
Maximum Birefringence – Δ = 0.020

Vermiculite for Crystallography
Chart shows birefringence interference colour range (at 30�m thickness) and does not take into account mineral colouration
Surface Relief – Low
Dispersion – Weak

X-Ray Powder Diffraction

Radiation – n α = 1.525 – 1.561 nβ = 1.545 – 1.581 nγ = 1.545 – 1.581
Data Set – Near Tonapah, Nevada, USA 1796
Data courtesy of RRUFF project at University of Arizona.
Powder Diffraction Data
d-spacing Intensity
14.15 – (10)
4.57 – (6)
2.615 – (5)
2.570 – (5)
2.525 – (4.5)
2.380-2.365 – (3.5b)
1.528 – (7)

Classification of Vermiculite

IMA status – Valid – first described prior to 1959 (pre-IMA) – “Grandfathered”
Strunz 8th edition ID – 8/H.21-10
Nickel-Strunz 10th (pending) edition ID – 9.EC.50
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
Dana 8th edition ID – 71.2.2d.3
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
Hey’s CIM Ref – 16.19.22
16 : Silicates Containing Aluminum and other Metals
19 : Aluminosilicates of Fe and Mg

Relationship of Vermiculite to other Species

Structurally related to group(s) – Montmorillonite-Vermiculite Group
Related Minerals – Nickel-Strunz Grouping –

Related Minerals – Nickel-Strunz Grouping
9.EC.05 Minnesotaite (Fe,Mg)3(Si4O10)(OH)2
9.EC.05 Talc Mg3(Si4O10)(OH)2
9.EC.05 Willemseite (Ni,Mg)3(Si4O10)(OH)2
9.EC.05 Ferripyrophyllite Fe23+(Si4O10)(OH)2
9.EC.05 Pyrophyllite Al2(Si4O10)(OH)2
9.EC.05 Boromuscovite KAl2(BSi3O10)(OH)2
9.EC.05 Celadonite K(Mg,Fe2+)Fe3+(Si4O10)(OH)2
9.EC.05 Chernykhite (Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2
9.EC.05 Montdorite (K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4
9.EC.05 Muscovite KAl2(AlSi3O10)(OH)2
9.EC.05 Nanpingite CsAl2(AlSi3O10)(OH,F)2
9.EC.05 Paragonite NaAl2(AlSi3O10)(OH)2
9.EC.05 Roscoelite K(V3+,Al)2(AlSi3O10)(OH)2
9.EC.05 Tobelite (NH4,K)Al2(AlSi3O10)(OH)2
9.EC.05 Aluminoceladonite K(Mg,Fe2+)Al(Si4O10)(OH)2

Related Minerals – Nickel-Strunz Grouping)
16.19.1 Indialite Mg2Al3(AlSi5O18)
16.19.2 Cordierite (Mg,Fe)2Al3(AlSi5O18)
16.19.3 Sekaninaite (Fe,Mg)2Al3(AlSi5O18)
16.19.4 Ferrogedrite Mg3(Si4O10)(OH)2
16.19.5 Staurolite (Fe2+,Mg,Mn)2Al4Si2O10(OH)4
16.19.6 Chloritoid Mg3(Si4O10)(OH)2

Other Names for Vermiculite

Synonyms – BrodrickiteCulsageeiteJefferisiteZonolite
Other Languages –

Other Languages
German Vermiculit
Russian Вермикулит
Simplified Chinese 蛭石
Spanish Vermiculita